Bis[4-bromo-2-(cyclopentyliminomethyl)phenolato]copper(II)
نویسنده
چکیده
The title compound, [Cu(C(12)H(13)BrNO)(2)], was prepared by the reaction of 5-bromo-salicylaldehyde, cyclo-pentyl-amine and copper(II) acetate in an ethanol solution. The Cu(II) atom lies on an inversion center and is four-coordinated in a square-planar geometry by two N and two O atoms from two 4-bromo-2-(cyclo-pentyl-imino-meth-yl)phenolate Schiff base ligands.
منابع مشابه
Bis[(E)-4-bromo-2-(ethoxyiminomethyl)phenolato-κ2 N,O 1]copper(II)
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The title complex, [Cu(C(17)H(11)BrNO)(2)], lies on a centre of inversion. The chelating Schiff base anions define a square-planar N(2)O(2) donor set. The nearly perpendicular orientation of the naphthyl residues of the chelate ring [dihedral angle = 82.12 (12)°] precludes the Cu(II) centre from additional coordination. In the refinement, the naphthyl rings were found to be disordered over two ...
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